Physical Chemistry

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By A.V. BELOZYOROV,

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The roots of ’physical arithmetic’ might be traced again to the very starting of man's makes an attempt to appreciate nature. certainly, arithmetic and physics have been a part of what used to be known as common philosophy. swift development of the actual sciences, aided by way of technological development and extending abstraction in mathematical study, prompted a separation of the sciences and arithmetic within the twentieth century.

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6] using (e,e) spectroscopy. The accuracy of the determined oscillator strength scales was estimated to be better than ±5%. , [5, 6]). 0 above the dipole breakdown limit of ~25 eV. However, its evaluation is possible quantum mechanically Electron-Collision-Induced Dissociative Ionization Cross Sections 35 using the suitable wave functions and transition probabilities corresponding to the production of cations. In case of dissociative ionization of polyatomic molecule SiH4, we have no reliable probabilities corresponding to different dissociative ionization processes.

4-5, pp. 395–404, 1995. 10. R. Basner, M. Schmidt, V. Tarnovsky, K. Becker, and H. Deutsch, “Dissociative ionization of silane by electron impact,” International Journal of Mass Spectrometry and Ion Processes, vol. 171, no. 1–3, pp. 83–93, 1998. 11. P. Haaland, “Dissociative ionization of silane,” Chemical Physics Letters, vol. 170, no. 2-3, pp. 146–152, 1990. 12. J. D. Morrison and J. C. Traeger, “Ionization and dissociation by electron impact III. CH4 and Sih4,” International Journal of Mass Spectrometry and Ion Physics, vol.

11, no. 3, pp. 289–300, 1973. 13. M. A. -K. Kim, W. Hwang, N. M. Weinberger, and M. E. Rudd, “Electron-impact total ionization cross sections of silicon and germanium hydrides,” The Journal of Chemical Physics, vol. 106, no. 23, pp. 9602–9608, 1997. 14. S. P. Khare, S. Prakash, and W. J. Meath, “Dissociative ionization of NH3 and H2O molecules by electron impact,” International Journal of Mass Spectrometry and Ion Processes, vol. 88, no. 2-3, pp. 299–308, 1989. 15. H. Deutsch, K. Becker, S. Matt, and T.

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